I'm no expert on programmes, but I have one that is pretty interesting (unfortunately not LFC related). It's Tom Finneys testimonial game played at Deepdale, PNE versus an England XI, consisting of many of the stars of 66.
I actually found the programme hidden in an old built-in piece of furniture in my terraced house in Preston. The day I found it, I rang Tom Finney's business, and asked to speak with him. I was amazed that they put me through to him, and asked if he'd sign it. He agreed, so I ran all the way there and he met me in reception and signed it for me. What a great bloke.
I'm not sure if it's worth anything like, what do you guys reckon?