It came out at 23:39 last night, I know because I uploaded it and checked that it'd gone out ok
I wonder why my iPhone Podcasts app sometimes takes a while to recognise a show is out? Like I say, if I'm at home, I can just log on the website, no problem at all. And generally, it's not that big a deal, as I often take in podcasts hours after they come out, when I'm out and about. It's only ever an issue for the Southampton special show - as it became redundant when it finally came through and then that Pink - but that one I was in the house as I watched the game at home.
I'll have a flick through the app settings in a bit and try deleting and reinstalling the podcasts app. Fairly certain it has to be a problem my end I think.
Edit: Another idea I had was to just install a third party podcast app alongside the official podcasts one and when I know something has dropped, refresh both.