That will be down to the pressure of the defender. I agree it still seems low though considering Mane's back post chance he missed, which was under more pressure and the ball was at a more awkward height was rated at 0,56 I believe. I would score this likewise.
I'm actually going to be controversial here and go against the grain:
I've long suspected that xG doesn't really use the defensive positions of the opponents when calculating their values. It's not that it's not relevant, it's just that it's not readily available in the data feeds and would therefore be a nightmare to include in the calcs. What they do offer however is:
a) 'Big chance' qualifier which is denoted as: 'Shot was deemed by Opta analysts an excellent opportunity to score – clear cut chance eg one on one'.
b) Goalkeeper position when shot is taken (this is not as useful/detailed as you would expect)
There's lots of other 'qualifiers' such as shot position, assist type, body part (which bassturnedtored has covered), type of play (ie. open play, setplay etc **) and a lot more which I won't go into detail about but none that I can see that accounts for the defenders when the shot is taken, just the two I've listed above.
The thing is I've just had a look at both Richarlison's chances on the opta feed and they are both listed by opta as 'Big Chances' so this doesn't add to the disparity that you've highlighted. I'm still trying to wrap my head around how these models are calculated based on what data opta provides and there's always a chance that they're getting defender positional data from somewhere I'm not privy to yet but my gut says that's not the case. You can extract whether the shot event type was blocked, (thus denoting players in the way), but not much more than that and it doesn't apply to both of those chances anyway. If somebody has evidence to the contrary I'm more than happy to be proved wrong on this, until then I'm crying foul on that stat - something's not quite right there.
** - btw Opta have the header listed as coming from a set piece play. I've watched the chance and the the ball is cleared out and delivered straight back in again. As a result understat seem to have categorised it as open play. Considering all the players are still in the box for the second attempt I'm more than likely to lean on Opta's definition of that play rather than understats', but I can definitely understand the ambiguity.